Physical sciences

The first flow bifurcation, in channels with a sudden geometry contraction, is controlled through shape optimization to delay the onset of asymmetry. First, we confirm the existence of a pitchfork type bifurcation instability, already reported in similar geometries. The global mode responsible for this bifurcation leads to asymmetric flow for Reynolds numbers beyond a critical value. Second, we propose a global shape optimization methodology to introduce small modifications in the channel geometry that lead to flows with enhanced stability. Our results include three contraction ratios C = 2, 4, and 8, where C is the ratio of upstream to downstream channel widths. The shape optimization aims at minimizing the growth rate of the unstable mode responsible for asymmetry. Sensitivity analysis is used to find an appropriate geometry parametrization, which is defined through super-elliptic curves, and limited to small deformations. Additionally, a dynamically updated surrogate model (based...

To capture the dynamics of modern Cyber-Physical Systems, hybrid system models are introduced to combine their continuous dynamics with the discrete ones. Unfortunately, one important negative issue can affect hybrid system models: the so-called Zeno phenomenon, which results in an infinite number of discrete transitions in a finite amount of time occurring during the model’s simulation that leads to inconsistent results. In this context, the paper investigates the use of a recently proposed numerical algorithm, based on the Infinity Computer methodology, to handle the Zeno phenomenon and evaluate it with respect to standard numerical methods by considering the hybrid system models of two exemplary Cyber-Physical Systems: the Water tanks and the Thermostat.

The present article deals with the analysis of thermal-bending stresses in a heated thin annular sector plate with simply supported boundary condition under transient temperature distribution using Berger’s approximate methods. The sectional heat supply is on the top face of the plate whereas the bottom face is kept at zero temperature. In this study, the solution of heat conduction is obtained by the classical method. The thermal moment is derived on the basis of temperature distribution, and its stresses are obtained using thermally induce resultant moment and resultant forces. The numerical calculations are obtained for the aluminium plate in the form of an infinite series involving Bessel functions, and the results for temperature, deflection, resultant bending moments and thermal stresses have been illustrated graphically with the help of MATHEMATICA software.

Chemically modified electrodes (CMEs) based on 2-phenyl-4-((4,6,8-trimethylazulen-1-yl)methylene)oxazol-5(4H)-one (M) were obtained by irreversible electrooxidation of M in millimolar solutions in 0.1 M tetrabutylammonium perchlorate (TBAP) in acetonitrile. These CMEs were characterized by a ferrocene redox probe, electrochemical impedance spectroscopy (EIS), X-ray photon spectroscopy (XPS), and scanning electron microscopy (SEM). The influence of the preparation conditions (charge and potential) was examined. The CMEs were finally used for the analysis of synthetic samples of heavy metal (HM) ions. The paper highlights the importance of potential and electropolymerization charge on the film properties, with accent on recognition of HMs, in order to identify the best conditions for their detection in water. The observed findings are relevant for further design and development of advanced materials based on azulenyl-phenyloxazolone for the analysis of HMs in water.

Rhodanine (R) is a heterocycle having complexing properties for heavy metal (HM) ions. Considering the similar electron-donating character of diethylaminobenzene and azulene, electrochemical characterization of (Z)-5-(azulen-1-ylmethylene)-2-thioxo-thiazolidin-4-one (R1) and 5-(4 diethylamino-benzylidene)-2-thioxo-thiazolidin-4-one (R2) was performed to establish their common features. Chemically modified electrodes based on R1 and R2 were compared for HM recognition. Evidence for the formation of films was provided by scanning and controlled potential electrolysis, and HM recognition experiments were performed using their films. Parallel studies for analysis of HMs by complexation in solution were performed by UV-Vis. The analogy between R1 and R2 created the premise for easier selection of compounds for certain applications. The performance of the chemically modified electrodes was evaluated as detection limits for HMs. The azulene monomer (R1) proved to be the best candidate for ...

Accurate forecasting of a building thermal performance can help to optimize its energy consumption. In addition, obtaining the Heat Loss Coefficient (HLC) allows characterizing the thermal envelope of the building under conditions of use. The aim of this work is to study the thermal inertia of a building developing a new methodology based on Long Short-Term Memory (LSTM) neural networks. This approach was applied to the Rectorate building of the University of Basque Country (UPV/EHU), located in the north of Spain. A comparison of different time-lags selected to catch the thermal inertia has been carried out using the CV(RMSE) and the MBE errors, as advised by ASHRAE. The main contribution of this work lies in the analysis of thermal inertia detection and its influence on the thermal behavior of the building, obtaining a model capable of predicting the thermal demand with an error between 12 and 21%. Moreover, the viability of LSTM neural networks to estimate the HLC of an in-use bu...

The Heat Loss Coefficient (HLC) characterizes the envelope efficiency of a building under in-use conditions, and it represents one of the main causes of the performance gap between the building design and its real operation. Accurate estimations of the HLC contribute to optimizing the energy consumption of a building. In this context, the application of black-box models in building energy analysis has been consolidated in recent years. The aim of this paper is to estimate the HLC of an existing building through the prediction of building thermal demands using a methodology based on Machine Learning (ML) models. Specifically, three different ML methods are applied to a public library in the northwest of Spain and compared; eXtreme Gradient Boosting (XGBoost), Support Vector Regression (SVR) and Multi-Layer Perceptron (MLP) neural network. Furthermore, the accuracy of the results is measured, on the one hand, using both CV(RMSE) and Normalized Mean Biased Error (NMBE), as advised by A...

Operating rooms are stringent controlled environments. All influential factors, in particular, airborne particles, must be within the limits established by regulations. Therefore, energy efficiency stays in the background, prioritizing safety and comfort in surgical areas. However, the potential of improvement in energy savings without compromising this safety is broad. This work presents a new procedure, based on calibrated simulations, that allows the identification of potential energy savings in an operating room, complying with current airborne particle standards. Dynamic energy and airborne particle models are developed and then simulated in TRNSYS and calibrated with GenOpt. The methodology is validated through experimental contrast with a real operating room of a hospital in Spain. A calibrated model with around 2% of error is achieved. The procedure determines the variation in particle concentration according to the flow rate of ventilation supplied and the occupancy of the ...

This document addresses the development of a novel methodology to identify the actual maintenance factor of the luminaires of an outdoor lighting installation in order to assess their lighting performance. The method is based on the combined use of Radiance, a free and open-source tool, for the modeling and simulation of lighting scenes, and GenOpt, a generic optimization program, for the calibration of the model. The application of this methodology allows the quantification of the deterioration of the road lighting system and the identification of luminaires that show irregularities in their operation. Values lower than 9% for the error confirm that this research can contribute to the management of street lighting by assessing real road conditions.

This manuscript integrates the experimental findings of recently developed epoxy-phase change material (PCM) formulations with modeling efforts aimed to determine the energy demands and savings derived from their use. The basic PCM system employed was composed of an epoxy resin, a thickening agent, and nonadecane, where the latter was the hydrocarbon undergoing the phase transformation. Carbon nanofibers (CNF) and boron nitride (BN) particulates were used as heat flow enhancers. The thermal conductivities, densities, and latent heat determined in laboratory settings were introduced in a model that calculated, using EnergyPlus software, the energy demands, savings and temperature profiles of the interior and the walls of a shelter for six different locations on Earth. A shipping container was utilized as exemplary dwelling. Results indicated that all the epoxy-PCM formulations had a positive impact on the total energy savings (between 16% and 23%) for the locations selected. The use ...

The chaperone-like activity of αA-crystallin has an important role in maintaining lens transparency. Previously we identified residues 70-88 as a chaperone site in αA-crystallin. In this study, we deleted the chaperone site residues to generate αAΔ70-76 and αAΔ70-88 mutants and investigated if there are additional substrate-binding sites in αA-crystallin. Both mutant proteins when expressed in E. coli formed inclusion bodies, and on solubilizing and refolding, they exhibited similar structural properties, with a 2- to 3-fold increase in molar mass compared to the molar mass of wild-type protein. The deletion mutants were less stable than the wild-type αA-crystallin. Functionally αAΔ70-88 was completely inactive as a chaperone, while αAΔ70-76 demonstrated a 40-50% reduction in anti-aggregation activity against alcohol dehydrogenase (ADH). Deletion of residues 70-88 abolished the ADH binding sites in αA-crystallin at physiological temperature. At 45°C, cryptic ADH binding site(s) beca...

We investigate the reach of future gravitational wave (GW) detectors in probing inflaton couplings with visible sector particles that can either be bosonic or fermionic in nature. Assuming reheating takes place through perturbative quantum production from vacuum in presence of classical inflaton background field, we find that the spectral energy density of the primordial GW generated during inflation becomes sensitive to inflaton-matter coupling. We conclude, obeying bounds from Big Bang Nucleosysthesis and Cosmic Microwave Background, that, e.g., inflaton-scalar couplings of the order of ~ 𝒪(10−20) GeV fall within the sensitivity range of several proposed GW detector facilities. However, this prediction is sensitive to the size of the inflationary scale, nature of the inflaton-matter interaction and shape of the potential during reheating. Having found the time-dependent effective inflaton decay width, we also discuss its implications for dark matter (DM) production from the therma...

Soft breaking of a symmetry requires an invariance of the dimension-4 part of the Lagrangian and non-trivial variation of the lower-dimensional part. However, in general, separation between the dim-4 and lower-dimensional Lagrangian is not invariant with respect to basis transformations of fields. Therefore, a natural question of the physical meaning of soft symmetry breaking arises. This problem is addressed here in the framework of two-Higgs-Doublet Models (2HDM). It has been shown, within these models, that in spite of the ambiguity corresponding to the separation between dim-4 and the lower-dimension Lagrangian, implications of the soft symmetry breaking could be formulated in terms of observables, i.e., they are physical and measurable. There are six global symmetries that can be imposed on the scalar sector of the generic 2HDM. Necessary and sufficient tree-level conditions for soft breaking of all of them have been formulated in terms of observables.

A reheating phase in the early universe is an essential part of all inflationary models during which not only the Standard Model (SM) quanta are produced but it can also shed light on the production of dark matter. In this work, we explore a class of reheating models where the reheating is induced by a cubic interaction of the inflaton ϕ to the SM Higgs boson h of the form ghϕMPlϕ|h|2 adopting the α-attractor T-model of inflation. Assuming inflaton as a background field such interaction implies a ϕ-dependent mass term of the Higgs boson and a non-trivial phase-space suppression of the reheating efficiency. As a consequence, the reheating is prolonged and the maximal temperature of the SM thermal bath is reduced. In particular, due to oscillations of the inflaton field the ϕ-dependent Higgs boson mass results in periodic transitions between phases of broken and unbroken electroweak gauge symmetry. The consequences of these rapid phase transitions have been studied in detail. A purely...

We discuss a perturbative and non-instantaneous reheating model, adopting a generic post-inflationary scenario with an equation of state w. In particular, we explore the Higgs boson-induced reheating, assuming that it is achieved through a cubic inflaton-Higgs coupling ϕ|H|2. In the presence of such coupling, the Higgs doublet acquires a ϕ-dependent mass and a non-trivial vacuum–expectation–value that oscillates in time and breaks the Standard Model gauge symmetry. Furthermore, we demonstrate that the non-standard cosmologies and the inflaton-induced mass of the Higgs field modify the radiation production during the reheating period.This, in turn, affects the evolution of a thermal bath temperature, which has remarkable consequences for the ultraviolet freeze-in dark matter production.

Symmetries of the Two-Higgs-Doublet Model (2HDM) potential that can be extended to the whole Lagrangian, i.e. the CP-symmetries CP1, CP2, CP3 and the Higgs-family symmetries Z2, U(1) and SO(3) are discussed. Sufficient and necessary conditions in terms of constraints on masses and physical couplings for the potential to respect each of these symmetries are found. Each symmetry can be realized through several alternative cases, each case being a set of relations among physical parameters. We will show that some of those relations are invariant under the renormalization group, but others are not. The cases corresponding to each symmetry group are illustrated by analyzing the interplay between the potential and the vacuum expectation values.

In face of the small-scale structure problems of the collisionless cold dark matter (DM) paradigm, a popular remedy is to introduce a strong DM self-interaction which can be generated nonperturbatively by a MeV-scale light mediator. However, if such a mediator is unstable and decays into SM particles, the model is severely constrained by the DM direct and indirect detection experiments. In the present paper, we study a model of a self-interacting fermionic DM, endowed with a light stable scalar mediator. In this model, the DM relic abundance is dominated by the fermionic DM particle which is generated mainly via the freeze-out of its annihilations to the stable mediator. Since this channel is invisible, the DM indirect detection constraints should be greatly relaxed. Furthermore, the direct detection signals are suppressed to an unobservable level since fermionic DM scatterings with a nucleon appear at one-loop level. By further studying the bounds from the CMB, supernovae and BBN o...

Recent dark matter (DM) direct searches place very stringent constraints on the possible DM candidates proposed in extensions of the Standard Model. There are however models where these constraints are avoided. One of the simplest and most striking examples comes from a straightforward Higgs-portal pseudo-scalar DM model featured with a softly broken U(1) symmetry. In this model the tree-level DM-nucleon scattering cross section vanishes in the limit of zero momentum transfer. It has also been argued that the leading-order DM-nucleon cross section appears at the one-loop level. In this work we have calculated the exact cross section in the zero momentum transfer at the leading order i.e., at the one-loop level of perturbative expansion. We have concluded that, in agreement with expectations, the amplitude for the scattering process is UV finite and approaches zero in the limit of vanishing DM masses. Moreover, we made clear that the finite DM velocity correction at tree level is sub...